Photo curable resin composition, imaging display device and production method thereof

ABSTRACT

A photocurable resin composition which hardly causes leakage and is easily formed into a desired shape and an image display device using this photocurable resin composition are provided. 
     Namely, a photocurable resin composition comprises a compound (A) having a photopolymerizable functional group and an oil gelling agent (B), is provided. Also, an image display device having a laminate structure including an image display unit having an image display part, a transparent protective plate, and a resin layer existent between the image display unit and the transparent protective plate, wherein the resin layer is a cured material of the above-described photocurable resin composition, is provided.

This application is a Divisional application of pending application Ser.No. 14/840,505, filed Aug. 31, 2015, application Ser. No. 14/840,505 isa Divisional application of application Ser. No. 13/848,138, filed Mar.21, 2013, which issued as U.S. Pat. No. 9,150,706, application Ser. No.13/848,138 is a non-provisional application of provisional ApplicationNo. 61/614,038, filed Mar. 22, 2012, the contents of each of which areincorporated herein by reference in their entirety.

BACKGROUND OF THE INVENTION

1. Technical Field

The present invention relates to a photocurable resin composition, animage display device using this photocurable resin composition, and amethod for manufacturing the same.

2. Background Art

Photocurable resin compositions are widely used as an adhesive; apressure-sensitive adhesive; a filler; an optical member such as anoptical wave guide, a member for solar batteries; a light emitting diode(LED), a phototransistor, a photodiode, an optical semiconductorelement, an image display device, an illumination device, etc.; a dentalmaterial; and the like.

For example, there is proposed a method in which in an image displaydevice, an air gap between a transparent protective plate or aninformation input device (for example, a touch panel, etc.) and adisplay surface of an image display unit, or an air gap between atransparent protective plate and an information input device, isdisplaced with a transparent material having a refractive index closerto that of the transparent protective plate, the information inputdevice, and the display surface of the image display unit than that ofair, thereby enhancing the transmittance and suppressing a lowering ofthe luminance or contrast of the image display device. Then, it isproposed to use an adhesive which is cured by ultraviolet rays orvisible rays as this transparent material (for example,JP-A-2008-83491). An example of a diagrammatic view of a liquid crystaldisplay device as this image display device is shown in FIG. 1. A liquidcrystal display device with a built-in touch panel is configured of atransparent protective plate (glass or plastic base material) 1, a touchpanel 2, a polarizing plate 3, and a liquid crystal display cell 4. Forthe purposes of preventing the breakage of the liquid crystal displaydevice, relaxing the stress and impact, and enhancing the visibility,there may be the case where a pressure-sensitive adhesive layer 5 isprovided between the transparent protective plate 1 and the touch panel2, and a pressure-sensitive adhesive layer 6 is further provided betweenthe touch panel 2 and the polarizing plate 3.

As the photocurable resin composition, those in a liquid form or filmform are known.

For example, JP-A-2009-1654 discloses a photocuring type transparentadhesive composition containing a urethane (meth)acrylate (A) having twoor more functional groups having an unsaturated double bond, a monomer(B) having one functional group having an unsaturated double bond, aphotopolymerization initiator (C), and a polythiol compound (D) havingtwo or more thiol groups.

In addition, JP-A-2011-74308 discloses a transparent pressure-sensitiveadhesive sheet composed of a photocurable resin composition containing acopolymer of a monomer component containing an alkyl (meth)acrylate inwhich the alkyl group has a carbon number of from 4 to 18, and the like.

Now, as a technology for gelling an oil, the addition of an oil gellingagent to the oil is carried out. The oil gelling agent is characterizedin that the molecule forms a network in the oil, thereby achievingthickening. It is possible to gel the oil by dispersing a low-molecularweight oil gelling agent in the oil under heating conditions and coolingthe dispersion to room temperature.

PRIOR ART Patent Literature

Patent Document 1: JP2008-83491A

Patent Document 2: JP2009-1654A

Patent Document 3: JP2011-74308A

SUMMARY OF THE INVENTION Problem to be Solved by the Invention

When the photocurable resin composition is in a liquid form as inJP-A-2009-1654 or the like, at the time of forming in a prescribedplace, there is involved such a problem that the photocurable resincomposition is liable to leak out from the subject prescribed place.

On the other hand, when the photocurable resin composition is in a sheetform (solid form) as in JP-A-2011-74308, though the problem of leakageis not caused, there is involved such a problem that the photocurableresin composition does not sufficiently deform after the shape of aprescribed place, thereby likely generating an air gap or the like inthe subject prescribed place.

An object of the present invention is to solve the foregoing problemsand to provide a photocurable resin composition which hardly causesleakage and is easily formed into a desired shape, an image displaydevice using this photocurable resin composition, and a method formanufacturing the same.

The present invention provides the following [1] to [11].

[1] A photocurable resin composition containing a compound (A) having aphotopolymerizable functional group and an oil gelling agent (B).[2] The photocurable resin composition as set forth in [1], wherein theoil gelling agent (B) is at least one member of a hydroxy fatty acid,dextrin ester of fatty acid, n-lauroyl-L-glutamic acid-α,β-dibutylamide,di-p-methylbenzylidene sorbitol glucitol,1,3:2,4-bis-O-benzylidene-D-glucitol,1,3:2,4-bis-O-(4-methylbenzylidene)-D-sorbitol,bis(2-ethylhexanoato)hydroxyaluminum, and compounds represented by thefollowing general formulae (1) to (12).

(In the genera formula (1), m is an integer of from 3 to 10; n is aninteger of from 2 to 6; R₁ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and X is sulfur or oxygen.

In the general formula (2), R₂ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and Y₁ is a bond or a benzene ring.

In the general formula (3), R₃ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and Y₂ is a bond or a benzene ring.

In the general formula (4), R₄ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (6), R₅ and R₆ are each independently a saturatedhydrocarbon group having a carbon number of from 1 to 20.

In the general formula (7), R₇ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (8), R₈ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (10), R₉ and R₁₀ are each independently asaturated hydrocarbon group having a carbon number of from 1 to 20.)

[3] The photocurable resin composition as set forth in [1] or [2],wherein the compound (A) having a photopolymerizable functional groupincludes a compound having an ethylenically unsaturated group.[4] The photocurable resin composition as set forth in any one of [1] to[3], further containing a photopolymerization initiator (C).[5] The photocurable resin composition as set forth in any one of [1] to[4], further containing a compound (D) which is liquid at 25° C.[6] The photocurable resin composition as set forth in any one of [1] to[5], further containing a compound (E) which is solid at 25° C.[7] An image display device having a laminate structure including animage display unit having an image display part, a transparentprotective plate, and a resin layer existent between the image displayunit and the transparent protective plate, wherein the resin layer is acured material of the photocurable resin composition as set forth in anyone of [1] to [6].[8] An image display device having a laminate structure including animage display unit having an image display part, a touch panel, atransparent protective plate, and a resin layer existent between thetouch panel and the transparent protective plate, wherein the resinlayer is a cured material of the photocurable resin composition as setforth in any one of [1] to [6].[9] The image display device as set forth in [7] or [8], wherein thetransparent protective plate has a level difference part.[10] A method for manufacturing an image display device comprisingallowing a photocurable resin composition to intervene in a gap betweenan image display unit having an image display part or a touch panel anda transparent protective plate and curing the photocurable resincomposition, wherein the photocurable resin composition as set forth inany one of [1] to [6] is allowed to intervene in the gap and cured uponirradiation with light from the side of the transparent protectiveplate.[11] The method for manufacturing an image display device as set forthin [10], wherein the transparent protective plate has a level differencepart.

Effect of the Invention

According to the present invention, it is possible to provide aphotocurable resin composition which hardly causes leakage and is easilyformed into a desired shape, an image display device using thisphotocurable resin composition, and a method for manufacturing the same.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagrammatic view showing a cross-sectional structure of anexample of an image display device.

FIG. 2 is a side cross-sectional view schematically showing anembodiment of a liquid crystal display device.

FIG. 3 is a side cross-sectional view schematically showing anembodiment of a liquid crystal display device having a touch panelmounted therein.

FIG. 4 is a graph showing evaluation results of Examples using analiphatic (meth)acrylate as the component (A).

FIG. 5 is a graph showing evaluation results of Examples using a(meth)acrylate having an aromatic ring as the component (A).

FIG. 6 is a graph showing evaluation results of Examples using a(meth)acrylate having an alicyclic group as the component (A).

FIG. 7 is a graph showing evaluation results of Examples using aheteroatom-based (meth)acrylate, a compound having a vinyl group, or acompound having an allyl group, respectively as the component (A).

FIG. 8 is a graph showing evaluation results of Examples using a polymerhaving a (meth)acryloyl group as the component (A).

FIG. 9 is a graph showing evaluation results of Reference Examples usingthe component (D).

DETAILED DESCRIPTION OF THE INVENTION [Photocurable Resin Composition]

The photocurable resin composition according to the present inventioncontains a compound (A) having a photopolymerizable functional group andan oil gelling agent (B).

The photocurable resin composition according to the present inventionhardly causes leakage and is easily formed into a desired shape. Thoughdetails of the reason for this are not elucidated yet, they may besupposed as follows.

In the compound (A) having a photopolymerizable functional group, theoil gelling agent (B) which is contained in the photocurable resincomposition reveals a noncovalent intermolecular interaction such ashydrogen bond, electrostatic bond, π-π interaction, van der Waalsforces, etc. and is mutually connected to form a fibrous conjugate(hereinafter also referred to as “self-organization”). According tothis, at least a part of the photocurable resin composition becomes amaterial in a physical gel form at room temperature of 25° C.(hereinafter also referred to as “gelled” or “gel form”). As a result,it may be supposed that the photocurable resin composition according tothe present invention hardly causes leakage as compared with a liquidand is easily formed into a desired shape as compared with a solid.

Next, each of the components of the photocurable resin composition isdescribed.

<Compound (A) Having a Photopolymerizable Functional Group>

The compound (A) having a polymerizable functional group (hereinafteralso referred to as “component (A)”) is not particularly limited so faras it is photocurable. A compound containing an ethylenicallyunsaturated group, which is curable with a photopolymerization initiatorcapable of generating a radical, such as a (meth)acryloyl group, a vinylgroup, an allyl group, etc.; a compound containing a cyclic ether group,which is curable with a photo acid generator capable of generating anacid, such as an epoxy group, etc.; and the like are preferable.However, from the standpoints of curability and transparency, a compoundcontaining an ethylenically unsaturated group is preferable, and acompound containing a (meth)acryloyl group is more preferable.

As the compound containing an ethylenically unsaturated group, a(meth)acrylate compound, a polymer having a (meth)acryloyl group, acompound having a vinyl group, a compound having an allyl group, and thelike are suitable. Next, these compounds and polymers are described inthis order.

Incidentally, in the present specification, the term “(meth)acrylate”means an “acrylate” and a corresponding “methacrylate”. Similarly, theterm “(meth)acryl” means an “acryl” and a corresponding “methacryl”, andthe term “(meth)acryloyl” means an “acryloyl” and a corresponding“methacryloyl”.

((Meth)Acrylate Compound)

Examples of the (meth)acrylate compound include (meth)acrylic acid;(meth)acrylic acid amide; (meth)acryloyl morpholine; an alkyl(meth)acrylate in which the alkyl group has a carbon number of from 1 to18, such as methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl(meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate,n-pentyl (meth)acrylate, n-hexyl (meth)acrylate, n-octyl (meth)acrylate,isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isodecyl(meth)acrylate, dodecyl (meth)acrylate (n-lauryl (meth)acrylate),isomyristyl (meth)acrylate, stearyl (meth)acrylate, etc.; an alkanedioldi(meth)acrylate in which the alkane has a carbon number of from 1 to18, such as ethylene glycol di(meth)acrylate, butanediol (meth)acrylate,nonanediol di(meth)acrylate, etc.; a polyfunctional (meth)acrylatehaving three or more (meth)acryloyl groups in the molecule thereof, suchas trimethylolpropane tri(meth)acrylate, tetramethylolmethanetri(meth)acrylate, tetramethylolmethane tetra(meth)acrylate,dipentaerythritol penta(meth)acrylate, dipentaerythritolhexa(meth)acrylate, etc.; glycidyl methacrylate; an alkenyl(meth)acrylate in which the alkenyl group has a carbon number of from 2to 18, such as 3-butenyl (meth)acrylate, etc.; a (meth)acrylate havingan aromatic ring, such as benzyl (meth)acrylate, phenoxyethyl(meth)acrylate, etc.; an alkoxypolyalkylene glycol (meth)acrylate suchas methoxytetraethylene glycol (meth)acrylate, methoxyhexaethyleneglycol (meth)acrylate, methoxyoctaethylene glycol (meth)acrylate,methoxynonaethylene glycol (meth)acrylate, methoxypolyethylene glycol(meth)acrylate, methoxyheptapropylene glycol (meth)acrylate,ethoxytetraethylene glycol (meth)acrylate, butoxyethylene glycol(meth)acrylate, butoxydiethylene glycol (meth)acrylate, etc.; a(meth)acrylate having an alicyclic group, such as cyclohexyl(meth)acrylate, isobornyl (meth)acrylate, dicyclopentanyl(meth)acrylate, etc.; a (meth)acrylate having a hydroxyl group, such as2-hydroxyethyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate,4-hydroxybutyl (meth)acrylate, etc.; tetrahydrofurfuryl (meth)acrylate;a (meth)acrylamide derivative such as N,N-dimethylaminoethyl(meth)acrylate, N,N-dimethylaminopropyl (meth)acrylamide, N,N-dimethyl(meth)acrylamide, N-isopropyl (meth)acrylamide, N,N-diethyl(meth)acrylamide, N-hydroxyethyl (meth)acrylamide, etc.; a(meth)acrylate having an isocyanate group, such as2-(2-methacryloyloxyethyloxy)ethyl isocyanate, 2-(meth)acryloyloxyethylisocyanate, etc.; a polyalkylene glycol mono(meth)acrylate such astetraethylene glycol mono(meth)acrylate, hexaethylene glycolmono(meth)acrylate, octapropylene glycol mono(meth)acrylate, dipropyleneglycol mono(meth)acrylate, tripropylene glycol mono(meth)acrylate,octapropylene glycol mono(meth)acrylate, etc.; a polyalkylene glycoldi(meth)acrylate; a (meth)acrylate having an isocyanuric ring skeleton;a (meth)acrylate having a siloxane skeleton; and the like. These may beused alone or in combination of two or more kinds thereof.

Incidentally, there may be the case where the alkyl (meth)acrylate inwhich the alkyl group has a carbon number of from 1 to 18, thealkanediol di(meth)acrylate in which the alkane has a carbon number offrom 1 to 18, the polyfunctional (meth)acrylate having three or more(meth)acryloyl groups in the molecule thereof, the glycidylmethacrylate, and the alkenyl (meth)acrylate in which the alkenyl grouphas a carbon number of from 2 to are generically named an “aliphatic(meth)acrylate”. In addition, there may be the case where the alkoxypolyalkylene glycol (meth)acrylate, the polyalkylene glycolmono(meth)acrylate, the polyalkylene glycol di(meth)acrylate, the(meth)acrylate having an isocyanuric ring skeleton, and the(meth)acrylate having a siloxane skeleton are generically named a“heteroatom-based (meth)acrylate”.

[Aliphatic (Meth)Acrylate]

Specifically, as the aliphatic (meth)acrylate, those represented by thefollowing general formulae (13) to (23) are suitable.

The compound of the general formula (13) is commercially available as,for example, FA-129AS (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

The compound of the general formula (14) is commercially available as,for example, LIGHT ESTER L (a trade name for lauryl methacrylate,manufactured by Kyoeisha Chemical Co., Ltd.) and is also commerciallyavailable as FA-112M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (15) is 2-ethylhexyl acrylate (EHA),is commercially available from, for example, Wako Pure ChemicalIndustries, Ltd., and is also commercially available as 2-ethylhexylacrylate from Nippon Shokubai Co., Ltd.

The compound of the general formula (16) is commercially available as,for example, LIGHT ACRYLATE IM-A (a trade name for isomyristyl acrylate(isomer mixture of C14), manufactured by Kyoeisha Chemical Co., Ltd.).

The compound of the general formula (17) is commercially available as,for example, FA-121M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (18) is commercially available as,for example, FA-112A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (19) is commercially available as,for example, FA-126AS (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

The compound of the general formula (20) is commercially available as,for example, VBMA (a name of an article made on an experimental basis,manufactured by Hitachi Chemical Co., Ltd.).

The compound of the general formula (21) is commercially available as,for example, LIGHT ACRYLATE TMP-A (a trade name manufactured by KyoeishaChemical Co., Ltd.).

The compound of the general formula (22) is commercially available as,for example, FA-125M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (23) is commercially available as,for example, LIGHT ESTER G (a trade name manufactured by KyoeishaChemical Co., Ltd.) (also referred to as “GMA”).

Among the foregoing compounds, from the viewpoint of transparency, thecompounds of the general formulae (13) to (19) are preferable.

From the viewpoint of gelation (self-organization), the compounds of thegeneral formulae (13) to (18) and (20) to (22) are preferable, and thecompounds of the general formulae (13) to (16) are more preferable.

From the viewpoint of step height covering properties, all of thecompounds of the general formulae (13) to (23) are preferable.

Incidentally, details of the step height covering properties are thosedescribed in the Examples.

From the viewpoint of low curing shrinkage ratio, the compounds of thegeneral formulae (13) to (16), (18), and (19) are preferable, and thecompounds of the general formulae (13) to (16) and (18) are morepreferable. If the compound has a low curing shrinkage ratio, a changeof the dimension before and after the photocuring is small, and a curedmaterial with good dimensional precision can be obtained.

From the viewpoint of low dielectric constant, the compounds of thegeneral formulae (13) to (16), (18), and (19) are preferable, and thecompounds of the general formulae (13) to (16) and (18) are morepreferable. If the compound has a low dielectric constant, when thephotocurable resin composition is used in, for example, filling an airgap of a touch panel, a malfunction can be suppressed.

[(Meth)Acrylate Having an Aromatic Ring]

As the (meth)acrylate having an aromatic ring, one or two or more kindsof compounds represented by the following formulae (a) to (c) and benzyl(meth)acrylate are suitably exemplified.

(In the general formula (a), R²¹ represents a hydrogen atom or a methylgroup; R²² represents a hydrogen atom, an alkyl group having a carbonnumber of from 1 to 12, or a phenyl group; and n represents an integerof from 1 to 20.)

(In the general formula (b), R²³ represents a hydrogen atom or a methylgroup; R²⁴ represents a hydrogen atom or a methyl group; and m and neach independently represent an integer of from 1 to 20.)

(In the general formula (c), R²⁵ represents a hydrogen atom or a methylgroup; and m and n each independently represent an integer of from 1 to20.)

Specifically, as the (meth)acrylate having an aromatic ring, thoserepresented by the following general formulae (24) to (36) are suitable.

(In the general formula (24), an average value of n is 4.)

The compound of the general formula (24) is commercially available as,for example, FA-314A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (25), an average value of n is 8.)

The compound of the general formula (25) is commercially available as,for example, FA-318A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (26) is commercially available as,for example, FA-BZM (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (27) is commercially available as,for example, FA-BZA (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (28), an average value of (m+n) is 10.)

The compound of the general formula (28) is commercially available as,for example, FA-321A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (29), an average value of (m+n) is 18.)

The compound of the general formula (29) is commercially available as,for example, FA-3218M (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

(In the general formula (30), an average value of (m+n) is 10.)

The compound of the general formula (30) is commercially available as,for example, FA-321M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (31), an average value of (m+n) is 30.)

The compound of the general formula (31) is commercially available as,for example, FA-323M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (32) is commercially available as,for example, LIGHT ACRYLATE PO-A (a trade name manufactured by KyoeishaChemical Co., Ltd.).

(In the general formula (33), an average value of (m+n) is 4.)

The compound of the general formula (33) is commercially available as,for example, FA-324M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (34), an average value of (m+n) is 4.) Thecompound of the general formula (34) is commercially available as, forexample, FA-324A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (35) is commercially available as,for example, FA-302A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (36) is commercially available as,for example, A-BPFE (a trade name manufactured by Shin-Nakamura ChemicalCo., Ltd.).

Among the foregoing compounds, from the viewpoint of transparency, thecompounds of the general formulae (24) to (32) are preferable, thecompounds of the general formulae (24) to (31) are more preferable, andthe compounds of the general formulae (24) to (27) are still morepreferable.

From the viewpoint of gelation (self-organization), the compounds of thegeneral formulae (24) to (25) and (28) to (36) are preferable, and thecompounds of the general formulae (24), (28), (29), and (33) to (36) aremore preferable.

From the viewpoint of step height covering properties, all of thecompounds of the general formulae (24) to (36) are preferable.

From the viewpoint of low curing shrinkage ratio, the compounds of thegeneral formulae (24), (25), (28) to (31), (35), and (36) arepreferable, and the compounds of the general formulae (24), (28), and(36) are more preferable.

From the viewpoint of low dielectric constant, the compounds of thegeneral formulae (24), (25), (28) to (31), (35), and (36) arepreferable, and the compounds of the general formulae (24), (28), and(36) are more preferable.

[(Meth)Acrylate Having an Alicyclic Group]

Specifically, as the (meth)acrylate having an alicyclic group, thoserepresented by the following general formulae (37) to (43) are suitable.

The compound of the general formula (37) is commercially available as,for example, LIGHT ACRYLATE DCP-A (a trade name for dimethyloltricyclodecane diacrylate, manufactured by Kyoeisha Chemical Co., Ltd.).

The compound of the general formula (38) is commercially available as,for example, FA-512M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (39) is commercially available as,for example, FA-512AS (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

The compound of the general formula (40) is commercially available as,for example, FA-513M (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

The compound of the general formula (41) is commercially available as,for example, FA-513AS (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

The compound of the general formula (42) is commercially available as,for example, LIGHT ACRYLATE IB-XA (a trade name for isobornyl acrylate,manufactured by Kyoeisha Chemical Co., Ltd.).

The compound of the general formula (43) is commercially available as,for example, FA-511AS (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

All of the compounds of the general formulae (37) to (43) are extremelyexcellent in the transparency.

From the viewpoint of gelation (self-organization), the compounds of thegeneral formulae (37) and (38) are more preferable.

From the viewpoint of step height covering properties, all of thecompounds of the general formulae (37) to (43) are preferable.

From the viewpoint of low curing shrinkage ratio, the compounds of thegeneral formulae (37) to (43) are preferable, and the compounds of thegeneral formulae (38) to (43) are more preferable.

From the viewpoint of low dielectric constant, the compounds of thegeneral formulae (37) to (43) are preferable, and the compounds of thegeneral formulae (38) to (43) are more preferable.

[Heteroatom-Based (Meth)Acrylate]

The heteroatom-based (meth)acrylate as referred to in the presentinvention is classified as a (meth)acrylate not containing an aromaticring and containing a lot of heteroatoms.

As the heteroatom-based (meth)acrylate, one or two or more kinds of apolyalkylene glycol di(meth)acrylate represented by the followingformula (d), an alkoxy polyalkylene glycol (meth)acrylate and apolyalkylene glycol mono(meth)acrylate represented by the followingformula (e), a (meth)acrylate having an isocyanuric ring skeleton, and a(meth)acrylate having a siloxane skeleton are suitably exemplified.

(In the general formula (d), R²⁶ represents a hydrogen atom or a methylgroup; X₁ represents an ethylene group, a propylene group, or anisopropylene group; and s represents an integer of from 2 to 20.)

(In the general formula (e), R represents an alkyl group having a carbonnumber of from 1 to 5; R²⁷ represents a hydrogen atom or a methyl group;X₁ represents an ethylene group, a propylene group, or an isopropylenegroup; and s represents an integer of from 2 to 20.)

Specifically, as the heteroatom-based (meth)acrylate, those representedby the following general formulae (44) to (49) are suitable.

The compound of the general formula (44) is commercially available as,for example, FA-731A (a trade name manufactured by Hitachi Chemical Co.,Ltd.).

(In the general formula (45), an average value of n is 7.)

The compound of the general formula (45) is commercially available as,for example, FA-P240A (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

The compound of the general formula (46) is commercially available as,for example, FA-731AT (a trade name manufactured by Hitachi ChemicalCo., Ltd.).

(In the general formula (47), an average value of n is 9.)

The compound of the general formula (47) is commercially available as,for example, LIGHT ACRYLATE 130A (a trade name manufactured by KyoeishaChemical Co., Ltd.).

The compound of the general formula (48) is commercially available as,for example, X-22-164AS (a trade name manufactured by Shin-Etsu ChemicalCo., Ltd.).

The compound of the general formula (49) is commercially available as,for example, SILAPLANE TM-0701 (a trade name manufactured by JNCCorporation) (chemical name: 3-tris(trimethylsiloxy)silylpropylmethacrylate) (hereinafter also referred to as “TRIS”).

Among the foregoing compounds, from the viewpoint of transparency, thecompounds of the general formulae (44) and (45) are preferable.

From the viewpoint of gelation (self-organization), the compounds of thegeneral formulae (44), and (46) to (49) are preferable, and thecompounds of the general formulae (46) to (49) are more preferable.

From the viewpoint of step height covering properties, all of thecompounds of the general formulae (44) to (49) are preferable.

From the viewpoint of low curing shrinkage ratio, the compounds of thegeneral formulae (46), (48), and (49) are preferable, and the compoundof the general formula (48) is more preferable.

From the viewpoint of low dielectric constant, the compounds of thegeneral formulae (46), (48), and (49) are preferable, and the compoundof the general formula (48) is more preferable.

(Polymer Having a (Meth)Acryloyl Group)

Examples of the polymer having a (meth)acryloyl group includepolybutadiene (meth)acrylate, polyisoprene (meth)acrylate, urethaneacrylate, epoxy acrylate, an acrylic resin having a (meth)acryloyl groupin a side chain thereof, and a modified material thereof. These may beused alone or in combination of two or more kinds thereof.

Specifically, as the polymer having a (meth)acryloyl group, thoserepresented by the following general formulae (50) to (52) are suitable.

The compound of the general formula (50) can be, for example, obtainedby allowing G-3000 (a trade name for α,ω-polybutadiene glycol,manufactured by Nippon Soda Co., Ltd.) to react with KARENZ MOI (a tradename for 2-isocyanatoethyl methacrylate, manufactured by Showa DenkoK.K.) (hereinafter also referred to as “PB-MOI”).

The compound of the general formula (51) is commercially available as,for example, TEAI-1000 (a trade name manufactured by Nippon Soda Co.,Ltd.).

The compound of the general formula (52) is commercially available as,for example, UC-203 (manufactured by Kuraray Co., Ltd., n=3, numberaverage molecular weight: 35,000) having a structure represented byUC-102 (manufactured by Kuraray Co., Ltd., n=2, number average molecularweight: 17,000).

All of the compounds of the general formulae (50) to (52) are veryexcellent in all of transparency, gelation (self-organization)performance, and low dielectric constant.

From the viewpoint of step height covering properties, all of thecompounds of the general formulae (50) to (52) are excellent.

From the viewpoint of low curing shrinkage ratio, the compounds of thegeneral formulae (50) and (52) are preferable.

(Compound having a vinyl group and compound having an allyl group)

Examples of the compound having a vinyl group and the compound having anallyl group include styrene, divinylbenzene, vinylpyrrolidone, triallylisocyanurate, 1,2-polybutadiene, and the like. These may be used aloneor in combination of two or more kinds thereof.

Specifically, as the compound having a vinyl group and the compoundhaving an allyl group, those represented by the following generalformulae (53) to (55) are suitable.

The compound of the general formula (53) is STC (styrene) and iscommercially available from, for example, Wako Pure Chemical Industries,Ltd.

The compound of the general formula (54) is commercially available asRICON 130 and RICON 131 (all of which are a trade name for polybutadienemainly composed of a 1,2-structural unit, manufactured by Cray Valley).

The compound of the general formula (55) is commercially available as,for example, TRIC (a trade name manufactured by Nippon Kasei ChemicalCo., Ltd.).

Among the foregoing compounds, from the viewpoints of transparency,gelation (self-organization), and step height covering properties, allof the compounds are more preferable.

From the viewpoint of low curing shrinkage ratio, the compound of thegeneral formula (54) is preferable. From the viewpoint of low dielectricconstant, the compounds of the general formulae (54) and (55) arepreferable.

(Content of the Compound (A) Having a Photopolymerizable FunctionalGroup)

The content of the compound (A) having a photopolymerizable functionalgroup is preferably from 0.5 to 99% by mass relative to the whole amountof the photocurable resin composition. When the content of the compound(A) having a photopolymerizable functional group is 0.5% by mass ormore, the photocuring can be sufficiently achieved, whereas when it isnot more than 99% by mass, the content of the oil gelling agent becomesrelatively large, so that the gelation can be sufficiently achieved.From this viewpoint, the content of the compound (A) having aphotopolymerizable functional group is more preferably from 1 to 90% bymass, and still more preferably from 2 to 85% by mass.

<Oil Gelling Agent (B)>

Examples of the oil gelling agent (B) (hereinafter also referred to as“component (B)” include a hydroxy fatty acid such as a hydroxystearicacid, in particular, 12-hydroxystearic acid, etc., a dextrin ester offatty acid such as dextrin ester of palmitic acid, etc.,n-lauroyl-L-glutamic acid-α,β-dibutylamide, di-p-methylbenzylidenesorbitol glucitol, 1,3:2,4-bis-O-benzylidene-D-glucitol,1,3:2,4-bis-O-(4-methylbenzylidene)-D-sorbitol,bis(2-ethylhexanoato)hydroxyaluminum, compounds represented by thefollowing general formulae (1) to (12), and the like. These may be usedalone or in combination of two or more kinds thereof.

In the general formula (1), m is an integer of from 3 to 10; n is aninteger of from 2 to 6; R₁ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and X is sulfur or oxygen.

In the general formula (2), R₂ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and Y₁ is a bond or a benzene ring.

In the general formula (3), R₃ is a saturated hydrocarbon group having acarbon number of from 1 to 20; and Y₂ is a bond or a benzene ring.

In the general formula (4), R₄ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (6), R₅ and R₆ are each independently a saturatedhydrocarbon group having a carbon number of from 1 to 20.

In the general formula (7), R₇ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (8), R₈ is a saturated hydrocarbon group having acarbon number of from 1 to 20.

In the general formula (10), R₉ and R₁₀ are each independently asaturated hydrocarbon group having a carbon number of from 1 to 20.

The content of the oil gelling agent (B) is preferably from 0.1 to 20%by mass relative to the whole amount of the photocurable resincomposition. When the content of the oil gelling agent (B) is 0.1% bymass or more, the gelation can be sufficiently achieved, whereas when itis not more than 20% by mass, the content of the compound (A) having aphotopolymerizable functional group becomes relatively large, so thatthe photocuring can be sufficiently achieved. From this viewpoint, thecontent of the oil gelling agent (B) is more preferably from 0.2 to 15%by mass, and still more preferably from 0.3 to 10% by mass.

<Photopolymerization Initiator (C)>

It is preferable that the photocurable resin composition according tothe present invention contains a photopolymerization initiator (C)(hereinafter also referred to as “component (C)”). According to this,after the material in a physical gel form containing the component (A)and the component (B) is formed into a prescribed shape, the component(A) can be three-dimensionally crosslinked, and the leakage can be moresuppressed.

This photopolymerization initiator (C) allows the curing reaction to beadvanced upon irradiation with active energy rays. The active energyrays as referred to herein mean ultraviolet rays, electron beams,a-rays, p-rays, γ-rays, or the like.

The photopolymerization initiator is not particularly limited, and it ispossible to use a known material such as a benzophenone-based material,an anthraquinone-based material, a benzoyl-based material, a sulfoniumsalt, a diazonium salt, an onium salt, etc.

Specifically, examples thereof include an aromatic ketone compound suchas benzophenone, N,N′-tetramethyl-4,4′-diaminobenzophenone (Michler'sketone), N,N-tetraethyl-4,4′-diaminobenzophenone,4-methoxy-4,4′-dimethylaminobenzophenone, α-hydroxyisobutylphenone,2-ethylanthraquinone, t-butylanthraquinone, 1,4-dimethylanthraquinone,1-chloroanthraquinone, 2,3-dichloroanthraquinone,3-chloro-2-methylanthraquinone, 1,2-benzoanthraquinone,2-phenylanthraquinone, 1,4-naphthoquinone, 9,10-phenanthraquinone,thioxanthone, 2-chlorothioxanthone, 1-hydroxycyclohexyl phenyl ketone,2,2-dimethoxy-1,2-diphenylethan-1-one,2-hydroxy-2-methyl-1-phenylpropan-1-one, 2,2-diethoxyacetophenone, etc.;a benzoin compound such as benzoin, methyl benzoin, ethyl benzoin, etc.;a benzoin ether compound such as benzoin methyl ether, benzoin ethylether, benzoin isobutyl ether, benzoin phenyl ether, etc.; a benzilcompound such as benzil, benzil dimethyl ketal, etc.; an acridinecompound such as an ester compound of β-(acridin-9-yl) (meth)acrylicacid, 9-phenylacridine, 9-pyridylacridine, 1,7-diacridinoheptane, etc.;a 2,4,5-triarylimidazole dimer such as a2-(o-chlorophenyl)-4,5-diphenylimidazole dimer, a2-(o-chlorophenyl)-4,5-di(m-methoxyphenyl)imidazole dimer, a2-(o-fluorophenyl)-4,5-diphenylimidazole dimer, a2-(o-methoxyphenyl)-4,5-diphenylimidazole dimer, a2-(p-methoxyphenyl)-4,5-diphenylimidazole dimer, a2,4-di(p-methoxyphenyl)-5-phenylimidazole dimer, a2-(2,4-dimethoxyphenyl)-4,5-diphenylimidazole dimer, a2-(p-methylmercaptophenyl)-4,5-diphenylimidazole dimer, etc.; anα-aminoalkylphenone-based compound such as2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-1-butanone,2-methyl-1-[4-(methylthio)phenyl]-2-morpholino-1-propanone, etc.; anacyl phosphine oxide-based compound such asbis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide, etc.;oligo(2-hydroxy-2-methyl-1-(4-(1-methylvinyl)phenyl)propanone); and thelike.

In addition, in particular, an a-hydroxyalkylphenone-based compound suchas 1-hydroxycyclohexyl phenyl ketone,2-hydroxy-2-methyl-1-phenyl-propan-1-one,1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propan-1-one, etc.;an acyl phosphine oxide-based compound such asbis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2,4,4-trimethyl-pentylphosphine oxide,2,4,6-trimethylbenzoyl-diphenylphosphine oxide, etc.;oligo(2-hydroxy-2-methyl-1-(4-(1-methylvinyl)phenyl)propanone); and acombination thereof are preferable as the polymerization initiator whichdoes not color the photocurable resin composition.

The content of the photopolymerization initiator (C) is preferably from0.1 to 5% by mass, more preferably from 0.2 to 3% by mass, and stillmore preferably from 0.3 to 2% by mass relative to the whole amount ofthe photocurable resin composition. When the content of thephotopolymerization initiator (C) is 0.1% by mass or more, thephotopolymerization can be favorably initiated. When the content of thephotopolymerization initiator (C) is not more than 5% by mass, thephotocurable resin composition is excellent in the step height coveringproperties and self-organization properties, and a hue of the obtainedcured material does not become yellowish.

<Compound (D) which is Liquid at 25° C.>

In addition, the photocurable resin composition according to the presentinvention may further contain a compound (D) which is liquid at 25° C.(hereinafter also referred to as “component (D)”). The compound (D)which is liquid at 25° C. may be added according to the purpose withinthe range where the self-organization properties are not impaired. Here,the compound which is liquid includes a compound having high viscosity.

Examples of the compound (D) which is liquid at 25° C. includedi-2-ethylhexyl phthalate (DOP), di-n-octyl phthalate, diisononylphthalate (DINP), diisodecyl phthalate (DIDP), diundecyl phthalate (thegeneral formula (56), DUP), 1,4-bis(3-mercaptobutyryloxy)butane,1,3,5-tris(3-mercaptobutyryloxyethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione,pentaerythritol tetrakis(3-mercaptobutyrate), liquid paraffin, anorganic solvent, and the like.

Incidentally, the pentaerythritol tetrakis(3-mercaptobutyrate) iscommercially available as, for example, KARENZ MT PE1 (manufactured byShowa Denko K.K., the general formula (57)).

These are used for the purpose of reducing the viscosity of thephotocurable resin composition to adjust the degree of gelation.

In addition, other examples of the compound (D) which is liquid at 25°C. include a liquid polymer such as an acrylic resin, liquidpolybutadiene composed mainly of a 1,4-structural unit, hydrogenatedpolybutadiene, hydrogenated polyisoprene, hydrogenated polyisobutene,etc. These are used for other purpose of realizing low curing shrinkageand low dielectric constant.

The acrylic resin which is liquid at 25° C. is preferably an acrylicresin containing a constituent unit derived from an alkyl (meth)acrylatein which the alkyl group has a carbon number of from 4 to 18. Inaddition, an acrylic resin containing a constituent unit derived from analkyl (meth)acrylate in which the alkyl group has a carbon number offrom 4 to 18 and a constituent unit derived from styrene or benzyl(meth)acrylate is more preferable.

In addition, the hydrogenated polyisobutene which is liquid at 25° C. iscommercially available as, for example, PARLEAM (a trade namemanufactured by NOF Corporation).

In addition, the liquid polybutadiene composed mainly of a1,4-structural unit is commercially available as, for example, POLYOIL(Zeon Corporation).

A number average molecular weight (Mn) of the liquid polymer ispreferably from 500 to 5,000, more preferably from 800 to 4,000, andespecially preferably from 1,000 to 3,000.

In the case of using the compound (D) which is liquid at 25° C., fromthe viewpoints of self-organization properties and transparency, itscontent is preferably from 1 to 99% by mass relative to the whole amountof the photocurable resin composition. From these viewpoints, thecontent of the compound (D) is more preferably from 2 to 98% by mass.

<Compound (E) which is Solid at 25° C.>

In addition, the photocurable resin composition according to the presentinvention may further contain a compound (E) which is solid at 25° C.(hereinafter also referred to as “component (E)”). The compound (E)which is solid at 25° C. may be added according to the purpose withinthe range where the self-organization properties are not impaired.

Examples of this compound (E) which is solid at 25° C. include aterpene-based hydrogenated resin and the like, and these are used forthe purpose of enhancing the pressure-sensitive adhesiveness of thephotocurable resin composition to adjust the degree of gelation. Theterpene-based hydrogenated resin is commercially available as, forexample, CLEARON P SERIES (a trade name manufactured by YasuharaChemical Co., Ltd.).

From the viewpoints of self-organization properties, transparency, andleakage resistance, the content of the compound (E) which is solid at25° C. is preferably from 0.1 to 20% by mass relative to the wholeamount of the photocurable resin composition. From these viewpoints, thecontent of the compound (E) is more preferably from 1 to 10% by mass.

[Other Additives]

The photocurable resin composition according to the present inventionmay contain various additives separately from the above-describedcomponents (A) to (E), as the need arises. In the present invention,examples of the various additives which can be contained include apolymerization inhibitor, an antioxidant, a light stabilizer, a silanecoupling agent, a surfactant, a leveling agent, and the like.

The polymerization inhibitor is added for the purpose of increasing thestorage stability of the photocurable resin composition, and examplesthereof include p-methoxyphenol and the like.

The antioxidant is added for the purpose of increasing theheat-resistant colorability of a cured material obtained by curing thephotocurable resin composition with light, and examples thereof includea phosphorus-based antioxidant such as triphenyl phosphite, etc.; aphenol-based antioxidant; a thiol-based antioxidant; and the like.

The light stabilizer is added for the purpose of increasing theresistance to light such as ultraviolet rays, etc., and examples thereofinclude HALS (hindered amine light stabilizer).

The silane coupling agent is added for the purpose of increasing theadhesion to a glass or the like, and examples thereof includemethyltrimethoxysilane, methyltriethoxysilane, phenyltrimethoxysilane,phenyltriethoxysilane, γ-aminopropyltrimethoxysilane,γ-aminopropyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane,γ-glycidoxypropylmethyldiethoxysilane,γ-glycidoxypropylmethyldiisopropenoxysilane, and the like.

The surfactant is added for the purpose of controlling the peelability,and examples thereof include a polydimethylsiloxane-based compound, afluorine-based compound, and the like.

The leveling agent is added for the purpose of imparting flatness to thephotocurable resin, and examples thereof include a silicon-basedcompound and a fluorine-based compound capable of decreasing the surfacetension, and the like.

These additives may be used alone, or a combination of a plurality ofadditives may be used. Incidentally, in the case of using such anadditive, its content is usually small as compared with the totalcontent of the components (A) to (E) and is generally from about 0.01 to5% by mass relative to the whole amount of the photocurable resincomposition.

<Manufacturing Method of Photocurable Resin Composition>

The manufacturing method of the photocurable resin composition is notparticularly limited, the photocurable resin composition can bemanufactured by mixing the components (A) and (B) and if desired, thecomponents (C) to (E) and the above-described additives and stirring themixture.

In addition, in the case where any one of the respective components issolid, it is preferable to heat the solid component for dissolution at atiming of at least one of before mixing and stirring, during mixing andstirring, and after mixing and stirring. According to this, therespective components are well dispersed and then cooled, therebyobtaining the photocurable resin composition.

Though the heating temperature is not particularly limited, in the caseof using 12-hydroxystearic acid as the oil gelling agent (B), theheating temperature is preferably from 60 to 150° C. When the heatingtemperature is 60° C. or higher, the 12-hydroxystearic acid can besufficiently dissolved. When the heating temperature is not higher than150° C., the high transparency can be kept.

Though the stirring time is not particularly limited, it is preferablyfrom 10 to 600 seconds, and more preferably from 20 to 300 seconds.

<Image Display Device>

Next, an image display device using the photocurable resin compositionaccording to the present invention is described.

The photocurable resin composition according to the present inventioncan be applied to various image display devices. Examples of the imagedisplay device include a plasma display panel (PDP), a liquid crystaldisplay (LCD), a cathode ray tube (CRT), a field emission display (FED),an organic EL display (GELD), a 3D display, an electronic paper (EP),and the like.

The photocurable resin composition according to the present inventioncan be suitably used for laminating various layers configuring the imagedisplay device. Examples of the various layers include a functionallayer having functionality, such as an antireflection layer, anantifouling layer, a dye layer, a hard coat layer, etc.; a multilayeredmaterial obtained by film-forming or laminating such a functional layeron a base material film such as a polyethylene film, a polyester film,etc.; a transparent protective plate such as a glass, an acrylic resin,an alicyclic polyolefin, a polycarbonate, etc.; a multilayered materialobtained by film-forming or laminating a functional layer having afunction of every kind on such a transparent protective plate; and thelike. In addition, the photocurable resin composition according to thepresent invention can be used as an optical filter by photocuring toform a cured material and then combining with such a multilayeredmaterial. In that case, it is, for example, suitable that thephotocurable resin composition according to the present invention iscoated on or filled in the multilayered material, followed by curing.

The antireflection layer may be any layer so far as it hasantireflection properties such that its reflectance against visiblelight is not more than 5%, and a layer obtained by treating atransparent base material such as a transparent plastic film, etc. by analready-known antireflection method can be used.

In addition, the antifouling layer is a layer for making stains hardlyattach onto the surface. For the purpose of reducing the surfacetension, an already-known layer constituted of a fluorine-based resin ora silicone-based resin can be used.

The dye layer is used for the purpose of increasing the color purity. Inthe case where the color purity of light emitting from an image displayunit such as a liquid crystal display unit, etc., the dye layer is usedfor reducing unnecessary light. The dye layer can be obtained bydissolving, in a resin, a dye capable of absorbing light in anunnecessary portion, followed by film-forming or laminating on a basematerial film such as a polyethylene film, a polyester film, etc.

The hard coat layer is used for increasing the surface hardness. As thehard coat layer, those obtained by film-forming or laminating an acrylicresin made of urethane acrylate, epoxy acrylate, etc., an epoxy resin,or the like on a base material film such as a polyethylene film, etc.can be used. Similarly, for the purpose of increasing the surfacehardness, those obtained by film-forming or laminating a hard coat layeron a transparent protective plate such as a glass, an acrylic resin, analicyclic polyolefin, a polycarbonate, etc. can also be used.

The photocurable resin composition according to the present inventioncan be used upon being laminated on a polarizing plate. In that case,the photocurable resin composition can be laminated on the viewingsurface side of the polarizing plate and can also be laminated on theopposite side thereto.

In the case of using the photocurable resin composition on the viewingsurface side of the polarizing plate, an antireflection layer, anantifouling layer, an hard coat layer, and the like can be furtherlaminated on the viewing surface side of the photocurable resincomposition, and in the case of using the photocurable resin compositionbetween the polarizing plate and the liquid crystal cell, a layer havingfunctionality can be laminated on the viewing surface side of thepolarizing plate.

In the case of forming such a laminate, the photocurable resincomposition can be laminated using a roll laminator, a laminator, avacuum laminator, a sheet laminator, or the like.

The photocurable resin composition is preferably disposed between theimage display unit of the image display device and the transparentprotective plate (protective panel) of the forefront surface on theviewing side and at an appropriate position on the viewing side.Specifically, the photocurable resin composition is preferably appliedbetween the image display unit and the transparent protective plate.

In addition, in an image display device in which a touch panel iscombined with an image display unit, the photocurable resin compositionis preferably applied between the touch panel and the image display unitand/or between the touch panel and the transparent protective plate(protective panel). However, in view of the configuration of the imagedisplay device, so far as the photocurable resin composition accordingto the present invention is applicable, it should not be construed thatthe present invention is limited to the above-described positions.

Liquid crystal display devices that are an example of the image displaydevice are hereunder described in detail by reference to FIGS. 2 and 3.

<Image Display Device of FIG. 2>

FIG. 2 is a cross-sectional view schematically showing an embodiment ofthe liquid crystal display device according to the present invention.The liquid crystal display device shown in FIG. 2 is configured of animage display unit 7 in which a backlight system 50, a polarizing plate22, a liquid display cell 10, and a polarizing plate 20 are laminated inthis order; a transparent resin layer 32 provided on the upper surfaceof the polarizing plate 20 working as the viewing side of the liquidcrystal display device; and a transparent protective plate (protectivepanel) 40 provided on the surface thereof. A level difference part 60provided on the surface of the transparent protective plate 40 is filledwith the transparent resin layer 32. Incidentally, the transparent resinlayer 32 is basically corresponding to the photocurable resincomposition according to the present embodiment. The thickness of thelevel difference part 60 varies depending upon the size of the liquidcrystal display device or the like. In the case where the thickness ofthe level difference part 60 is from 30 μm to 100 μm, it is especiallyuseful to use the photocurable resin composition according to thepresent embodiment.

<Liquid Crystal Display Device of FIG. 3>

FIG. 3 is a cross-sectional view schematically showing a liquid crystaldisplay device having a touch panel mounted thereon, which is anembodiment of the liquid crystal display device according to the presentinvention. The liquid crystal display device shown in FIG. is configuredof an image display unit 7 in which a backlight system 50, a polarizingplate 22, a liquid display cell 10, and a polarizing plate 20 arelaminated in this order; a transparent resin layer 32 provided on theupper surface of the polarizing plate 20 working as the viewing side ofthe liquid crystal display device; a touch panel 30 provided on theupper surface of the transparent resin layer 32; a transparent resinlayer 31 provided on the upper surface of the touch panel 30; and atransparent protective plate 40 provided on the surface thereof. A leveldifference part 60 provided on the surface of the transparent protectiveplate 40 is filled with the transparent resin layer 31. Incidentally,the transparent resin layer 31 and the transparent resin layer 32 arebasically corresponding to the photocurable resin composition accordingto the present embodiment.

The level difference part 60 is provided for the purpose of, forexample, at the time of providing input/output wirings in thesurroundings of the information input device and the image display unit,allowing the wirings to be not seen or hardly seen from the side of thetransparent protective plate. From the viewpoint of allowing the wiringsto be not seen or hardly seen, the level difference part 60 ispreferably made of a light-shielding material. However, the leveldifference part 60 may be provided for other purpose such as decoration,etc. and may be transparent. Though this level difference part 60 isprovided on the lower surface of the transparent protective plate 40(surface on the side coming into contact with the transparent resinlayer 31), it may also be provided on the upper surface (surface on thefar side against the transparent resin layer 31). Though this leveldifference part 60 is made of a material different from that of thetransparent protective plate 40, it may be made of the same material,and these may be integrally formed. Though this level difference part 60has a framework shape along the peripheral edge of the lower surface ofthe transparent protective plate 40, it should not be construed that thepresent invention is limited thereto. The planar view shape can beformed in an arbitrary shape such as a framework shape in which a partor the whole of the level difference part 60 does not follow theperipheral edge of the lower surface of the transparent protective plate40, a U-shape, an L-shape, a linear shape, a wave shape, a dotted lineshape, a lattice shape, a curved shape, etc. The same is also applicableto the level difference part 60 of the liquid crystal display device ofFIG. 2.

Incidentally, in the liquid crystal display device of FIG. 3, though thetransparent resin layer intervenes in each of between the image displayunit 7 and the touch panel 30 and between the touch panel 30 and thetransparent protective plate 40, the transparent resin layer mayintervene in at least one of them. In addition, in the case where thetouch panel is of an on-cell type, the touch panel and the liquidcrystal display cell are integrated. Specific examples thereof includeone in which the liquid crystal display cell 10 of the liquid crystaldisplay device of FIG. 2 is replaced by one of an on-cell type.

In addition, in recent years, the development of a liquid crystaldisplay cell having a touch panel function installed therein, which iscalled an in-cell type touch panel, is advanced. A liquid crystaldisplay device equipped with such a liquid crystal display cell isconfigured of a transparent protective plate, a polarizing plate, and aliquid crystal display cell (touch panel function-provided liquidcrystal display cell), and the photocurable resin composition accordingto the present invention can also be suitably used for a liquid crystaldisplay device adopting such an in-cell type touch panel.

<Liquid Crystal Display Devices of FIGS. 2 and 3>

According to the liquid crystal display devices shown in FIGS. 2 and 3,since the photocurable resin composition according to the presentembodiment is provided as the transparent resin layer 31 or 32, theseliquid crystal display devices have impact resistance, and an imagewhich is free from ghost reflections, is clear, and is high in contrastis obtained.

For the liquid crystal display cell 10, those constituted of a liquidcrystal material which is well-known in the art can be used. Inaddition, though the liquid crystal display cell is classified into a TN(twisted nematic) mode, an STN (super-twisted nematic) mode, a VA(vertical alignment) mode, an IPS (in-place-switching) mode, or the likedepending upon the control method of the liquid crystal material, in thepresent invention, the liquid crystal display cell may be a liquidcrystal display cell adopting any control method.

As for the polarizing plates 20 and 22, a polarizing plate which isgeneral in the art can be used. The surface of such a polarizing platemay be subjected to a treatment such as anti-reflection, antifouling,hard coating, etc. Such a surface treatment may be applied to onesurface or both surfaces of the polarizing plate.

As for the touch panel 30, a touch panel which is generally used in theart can be used. The touch panel 30 includes, for example a resistivemembrane system which finger pressure or pressure of object etc. make anelectrode contact, an electrostatic capacitance type which detect thechange of the electrostatic capacitance when a finger or an objecttouches the surface, and an inductive coupling type. The transparentresin layer of the present invention is especially preferable for aliquid crystal display device which has an electrostatic capacitancetype touch panel. A touch panel having a structure of a transparentelectrode built on a base substrate is exemplified for the electrostaticcapacitance type touch panel. The base substrate includes a glasssubstrate, polyethylene terephthalate film, cycloolefin polymer film,etc., for example. The transparent electrode includes metal oxides suchas ITO (Indium Tin Oxide), for example. The thickness of the basesubstrate falls within the range of 20-1000 μm. The thickness of thetransparent electrode falls within the range of 10-500 nm.

Though the transparent resin layer 31 or 32 can be, for example, formedin a thickness of from 0.02 mm to 3 mm, from the viewpoints of stepheight covering properties and workability, it is preferably from 0.1 to1 mm, and more preferably 0.15 mm (150 μm) to 0.5 mm (500 μm). Inparticular, in the photocurable resin composition according to thepresent embodiment, by making the film thick, a much more excellenteffect can be exhibited, and such can be suitably adopted in the case offorming the transparent resin layer 31 or 32 of 0.1 mm or more.

In addition, the light transmittance of the transparent resin layer 31or 32 against light beams in a visible light region (wavelength: 380 to780 nm) is preferably 80% or more, more preferably 90% or more, andstill more preferably 95% or more.

As for the transparent protective plate 40, a general opticaltransparent substrate can be used. Specific examples thereof include aplate of an inorganic material such as a glass, quartz, etc., a resinplate such as an acrylic resin, an alicyclic polyolefin, apolycarbonate, etc., and a resin sheet such as a thick polyester sheet,etc. In the case where a high surface hardness is required, a plate suchas a glass, an acrylic resin, an alicyclic polyolefin, etc. ispreferable, and a glass plate is more preferable. In the case wherethinness or lightness is required, an acrylic resin, an alicyclicpolyolefin, or a polycarbonate is preferable. The surface of such atransparent protective plate may be subjected to a treatment such asanti-reflection, antifouling, hard coating, etc. Such a surfacetreatment may be applied to one surface or both surfaces of thetransparent protective plate. The transparent protective plate can alsobe used in combination of plural sheets thereof.

The backlight system 50 is representatively configured of reflectionmeans such as an reflection plate, etc. and illumination means such as alamp, etc.

As for a material of the level difference part 60, for example, anacrylic resin composition containing a black pigment, a low-meltingpoint glass containing a metal oxide, and the like are used.

<Manufacturing Method of Image Display Device> (Manufacturing Method ofLiquid Crystal Display Device of FIG. 2)

The liquid crystal display device of FIG. 2 can be manufactured by amanufacturing method including a step of allowing the photocurable resincomposition according to the present embodiment to intervene between theimage display unit 7 and the transparent protective plate (protectivepanel) 40 having the level difference part 60.

That is, the photocurable resin composition according to the presentinvention is formed on the surface side of the transparent protectiveplate (protective panel) 40 on which the level difference part 60 isformed. The formation may be carried out by coating the photocurableresin composition according to the present invention on the transparentprotective plate (protective panel) 40. In addition, the formation mayalso be carried out by previously forming the photocurable resincomposition in a gel form on a release sheet, bringing the photocurableresin composition in a gel form into contact with the transparentprotective plate (protective panel) 40, and pressing the assembly,followed by releasing the release sheet.

Thereafter, the resultant is superimposed on the upper surface of thepolarizing plate 20, and these are laminated using the above-describedlaminator or the like.

After laminating using the laminator or the like, in the case where anair bubble is observed in the photocurable resin composition, it ispreferable to carry out antifoaming using an autoclave or the like whileadjusting a degree of pressurization at a prescribed temperature. Inaddition, defoaming can be carried out under reduced pressure, too.

Thereafter, the photocurable resin composition is cured upon irradiationwith light to form the transparent resin layer 32, whereby the imagedisplay device of FIG. 2 can be suitably manufactured. As for thisirradiation with light, it is preferable to perform irradiation ofultraviolet rays from the side of the transparent protective plate 40,the side of the image display unit 7, and the side of the image displaydevice. According to this, reliability under high-temperaturehigh-humidity conditions (reduction of air bubble generation andsuppression of peeling) and adhesive strength can be enhanced. From theviewpoint of more enhancing reliability under high-temperaturehigh-humidity conditions, it is preferable to perform irradiation ofultraviolet rays from the side of the image display unit 7 not having alevel difference part. Though the dose of the ultraviolet rays is notparticularly limited, it is preferably from about 500 to 5,000 mJ/cm².

(Manufacturing Method of Liquid Crystal Display Device of FIG. 3)

The liquid crystal display device of FIG. 3 can be manufactured by amanufacturing method including a step of allowing the photocurable resincomposition according to the present embodiment to intervene between theimage display unit 7 and the touch panel 30 and/or between the touchpanel 30 and the transparent protective plate (protective panel) 40.

The transparent resin layer 31 can be manufactured by the same method asthat of the transparent resin layer of FIG. 2. The transparent resinlayer 32 can be manufactured by the same method as that of thetransparent resin layer 32 of FIG. 2, except for coating thephotocurable resin composition on the touch panel 30 in place of thetransparent protective plate (protective panel) 40.

In the case of curing the photocurable resin composition according tothe present invention, from the standpoint of more highly suppressing awarpage of the substrate of the transparent protective plate, the imagedisplay unit, or the like, the curing shrinkage ratio is preferably lessthan 10%, more preferably less than 5%, still more preferably less than2%, and especially preferably less than 1%. When the curing shrinkageratio is less than 10%, the warpage which may be generated in the imagedisplay unit can be sufficiently suppressed, and in the case where thephotocurable resin composition is used for the image display device, thegeneration of inconvenience such as color unevenness, etc. can beprevented from occurring.

In the case of using the photocurable resin composition according to thepresent invention between the touch panel and the transparent protectivelayer, a dielectric constant at 100 Hz of a cured material of thephotocurable resin composition is preferably not more than 7, morepreferably not more than 5, still more preferably not more than 4, andespecially preferably not more than 3. From the viewpoint of practicaluse, a lower limit value of the dielectric constant is preferably 2 ormore.

EXAMPLES

The present invention is hereunder described with reference to thefollowing Examples. Incidentally, it should not be construed that thepresent invention is limited to these Examples.

[Evaluation]

Photocurable resin compositions obtained in the respective Examples andComparative Examples were evaluated in the following test methods.

(1) Step Height Covering Properties:

A photocurable resin composition sealed in a 5-mL syringe was coated ona glass substrate of 58 mm×86 mm×0.7 mm (thickness).

Subsequently, on one side of the photocurable resin composition on whichthe glass substrate was not laminated, a glass substrate (leveldifference: 60 μm) having a level difference part, the outer peripheralportion of which had been printed so as to have a thickness of 60 μm,was laminated so as to interpose the photocurable resin compositiontherebetween by using a laminator. Incidentally, the glass substratehaving a level difference part, the outer peripheral portion of whichhad been printed, has the same outer dimension as that of the glasssubstrate, and it has an opening having an inner dimension of 45 mm×68mm. The above-described glass substrate was used in placed of aninformation input device or an image display unit and evaluated for thestep height covering properties.

(Evaluation criteria)A: The photocurable resin composition can be filled leaving no air gapin the level difference part without causing leakage.B: The photocurable resin composition flows out into the surroundingsfrom the top of the glass substrate.

(2) Evaluation of Self-Organization Properties:

A photocurable resin composition was added in a 2-mL screw tube andallowed to stand in an oven at 100° C. (forced convection constanttemperature oven: DN-400, manufactured by Yamato Scientific Co., Ltd.)until the oil gelling agent was dissolved. Subsequently, the solutionwas rapidly made uniform using a planetary centrifugal mixer, ARE-250(manufactured by Thinky Corporation) under conditions at 2,000 rpm for20 seconds and then allowed to stand at 25° C. for 30 minutes.Thereafter, the screw tube was inclined at about 60° and allowed tostand for 3 minutes, and the self-organization properties were thenevaluated.

(Evaluation Criteria)

4: The photocurable resin composition does not flow and keeps the shape.3: Though the photocurable resin composition keeps the gel state as awhole, it has fluidity slightly.2: The photocurable resin composition is separated into the gel stateand the liquid state.1: The photocurable resin composition is entirely liquid and hasfluidity.

(3) Evaluation of Transparency:

2 g of a photocurable resin composition was added in a 2-mL screw tubeand allowed to stand in an oven at 100° C. (forced convection constanttemperature oven: DN-400, manufactured by Yamato Scientific Co., Ltd.)until the oil gelling agent was dissolved. Subsequently, the solutionwas rapidly made uniform using a planetary centrifugal mixer, ARE-250(manufactured by Thinky Corporation) under conditions at 2,000 rpm for20 seconds and then allowed to stand at 25° C. for 30 minutes. Thetransparency of the contents of the screw tube was evaluated.

(Evaluation Criteria)

4: Even when the contents are made to look under a fluorescent lamp, anyturbidity is not observed.3: When the contents are made to look under a fluorescent lamp, it isnoted that the contents are turbid.2: The contents are slightly turbid.1: The contents are turbid to such a degree that when seen from theobserver side, the opposite side is not distinctly seen.

(4) Dielectric Constant:

A release PET film (IUPILON A63 manufactured by Teijin DuPont) wasplaced on the surface of a glass substrate, a circular frame (thickness:2 mm, inner diameter: 56 mm) made of a silicon rubber was placedthereon, and a photocurable resin composition was flown into the insideof the frame. A release PET film was further placed thereon, and UVirradiation was performed on the surface one by one (performed dose onone surface: 1 J/cm²) to obtain a molded body. In the molded body, therelease PET film was released to obtain a cured film of the photocurableresin composition. The thickness (d) of this cured film was measuredusing a micrometer (a product number: 543-285B ID-C112RB, manufacturedby Mitutoyo Corporation). Thereafter, an aluminum plate (thickness: 2mm) having a diameter of 56 mm was laminated on one surface of the curedfilm, and a copper foil (thickness: 80 μm) having a diameter of 36 mmand a ring-shaped copper foil (thickness: 80 μm) having an outerdiameter of 54 mm and an inner diameter of 40 mm were laminated in thisorder on the other surface, thereby preparing a measurement sample. Thismeasurement sample was held with a measurement jig “HP16451B”,manufactured by Hewlett-Packard Company, and its electrostatic capacity(C) was measured under conditions at 25° C. and at a frequency of 100kHz using an analyzer “HP4275A”, manufactured by Hewlett-Packard Companyand then substituted for the following equation to determine adielectric constant ∈_(r). Here, ∈₀ is a vacuum dielectric constant.

C=∈ ₀×∈_(r)×(π×18 mm×18 mm)/d

(5) Curing Shrinkage Ratio:

A photocurable resin composition was dropped onto a release PET film(“IUPILON A63”, manufactured by Teijin DuPont), and another sheet of arelease PET film (“IUPILON A63”, manufactured by Teijin DuPont) waslaminated so as to have a film thickness of 175 μm. Ultraviolet rayirradiation was performed at a dose of 1,000 mJ/cm² from the side of oneof the release PET films by using an ultraviolet ray irradiationapparatus, thereby fabricating a transparent sheet having thephotocurable resin composition cured therein. This transparent sheet andthe photocurable resin composition before curing were measured for aspecific density using an electronic densimeter (“SD-200L”, manufacturedby Alfa Mirage Co., Ltd.), and the curing shrinkage ratio was calculatedaccording to the following equation.

Curing shrinkage ratio (%)=[{(Specific gravity of resin compositionafter curing)−(Specific gravity of resin composition beforecuring)}/(Specific gravity of resin composition after curing)]×100

Manufacturing Example 1

A compound (A1) having a photopolymerizable functional group wasmanufactured according to the following operations.

9.9 g of lauryl acrylate (manufactured by Kyoeisha Chemical Co., Ltd.),0.1 g of 4-hydroxybutyl acrylate (HBA, manufactured by Nippon KaseiChemical Co., Ltd.), 0.15 g of n-octyl mercaptan (manufactured by WakoPure Chemical Industries, Ltd.), and 0.05 g of PERBUTYL 0 (manufacturedby NOF Corporation) were charged in a screw tube, and after stirring,the screw tube was put in a water bath at 80° C. and heated for 4 hours.Subsequently, the resulting screw tube was heated in a forced convectionconstant temperature oven (DN-400, manufactured by Yamato ScientificCo., Ltd.) at 100° C. for one hour and then taken out from the forcedconvection constant temperature oven, followed by allowing it to standuntil the temperature reached room temperature. Subsequently, 0.0051 gof methyl ether hydroquinone (manufactured by Wako Pure ChemicalIndustries, Ltd.) and 0.108 g of 2-isocyanatoethyl isocyanate (“KARENZMOI”, manufactured by Showa Denko K.K.) were charged. The resultingscrew tube was heated in a bath at 60° C. for 3 hours, thereby obtainingan acrylic resin (A1) having a methacryloyl group in a side chainthereof.

Manufacturing Example 2

An acrylic resin (A2) having a methacryloyl group in a side chainthereof was obtained by carrying out the same operations as those inManufacturing Example 1, except for using 2-ethylhexyl acrylate(manufactured by Hitachi Chemical Co., Ltd.) in place of the laurylacrylate.

Manufacturing Example 3

A compound (D) which is liquid at 25° C. was manufactured according tothe following operations.

4 g of styrene (manufactured by Wako Pure Chemical Industries, Ltd.), 6g of lauryl acrylate (“FA-112A”, manufactured by Hitachi Chemical Co.,Ltd.), 0.15 g of n-octyl mercaptan (manufactured by Wako Pure ChemicalIndustries, Ltd.), and 0.05 g of PERBUTYL 0 (manufactured by NOFCorporation) were charged in a screw tube, and after stirring, the screwtube was put in a water bath at 80° C. and heated for 4 hours.Subsequently, the resulting screw tube was heated in an oven at 100° C.for one hour, thereby obtaining a compound (D) which is liquid at 25° C.(number average molecular weight: 2,000).

Manufacturing Example 4

4 g of benzyl acrylate (“FA-BZA”, manufactured by Hitachi Chemical Co.,Ltd.), 6 g of lauryl acrylate (“FA-112A”, manufactured by HitachiChemical Co., Ltd.), 0.15 g of n-octyl mercaptan (manufactured by WakoPure Chemical Industries, Ltd.), and 0.05 g of PERBUTYL O (manufacturedby NOF Corporation) were charged in a screw tube, and after stirring,the screw tube was put in a water bath at 80° C. and heated for 4 hours.Subsequently, the resulting screw tube was heated in an oven at 100° C.for one hour, thereby obtaining a compound (D) which is liquid at 25° C.(number average molecular weight: 2,000).

Manufacturing Example 5

4 g of benzyl acrylate (“FA-BZA”, manufactured by Hitachi Chemical Co.,Ltd.), 6 g of 2-ethylhexyl acrylate (manufactured by Wako Pure ChemicalIndustries, Ltd.), 0.15 g of n-octyl mercaptan (manufactured by WakoPure Chemical Industries, Ltd.), and 0.05 g of PERBUTYL 0 (manufacturedby NOF Corporation) were charged in a screw tube, and after stirring,the screw tube was put in a water bath at 80° C. and heated for 4 hours.Subsequently, the resulting screw tube was heated in an oven at 100° C.for one hour, thereby obtaining a compound (D) which is liquid at 25° C.(number average molecular weight: 2,000).

Manufacturing Example 6

4 g of benzyl acrylate (“FA-BZA”, manufactured by Hitachi Chemical Co.,Ltd.), 6 g of isomyristyl acrylate (“LIGHT ACRYLATE IM-A”, manufacturedby Kyoeisha Chemical Co., Ltd.), 0.15 g of n-octyl mercaptan(manufactured by Wako Pure Chemical Industries, Ltd.), and 0.05 g ofPERBUTYL 0 (manufactured by NOF Corporation) were charged in a screwtube, and after stirring, the screw tube was put in a water bath at 80°C. and heated for 4 hours. Subsequently, the resulting screw tube washeated in an oven at 100° C. for one hour, thereby obtaining a compound(D) which is liquid at 25° C. (number average molecular weight: 2,000).

Manufacturing Example 7

4 g of dicyclopentanyl acrylate (“FA-513AS”, manufactured by HitachiChemical Co., Ltd.), 6 g of 2-ethylhexyl acrylate (manufactured by WakoPure Chemical Industries, Ltd.), 0.15 g of n-octyl mercaptan(manufactured by Wako Pure Chemical Industries, Ltd.), and 0.05 g ofPERBUTYL 0 (manufactured by NOF Corporation) were charged in a screwtube, and after stirring, the screw tube was put in a water bath at 80°C. and heated for hours. Subsequently, the resulting screw tube washeated in an oven at 100° C. for one hour, thereby obtaining a compound(D) which is liquid at 25° C. (number average molecular weight: 2,000).

Manufacturing Example 8

4 g of nonylphenoxy polyethylene glycol acrylate (“FA-314A”,manufactured by Hitachi Chemical Co., Ltd.), 6 g of 2-ethylhexylacrylate (manufactured by Wako Pure Chemical Industries, Ltd.), 0.15 gof n-octyl mercaptan (manufactured by Wako Pure Chemical Industries,Ltd.), and 0.05 g of PERBUTYL 0 (manufactured by NOF Corporation) werecharged in a screw tube, and after stirring, the screw tube was put in awater bath at 80° C. and heated for hours. Subsequently, the resultingscrew tube was heated in an oven at 100° C. for one hour, therebyobtaining a compound (D) which is liquid at 25° C. (number averagemolecular weight: 2,000).

Manufacturing Example 9

4 g of SILAPLANE TM-0701 (a trade name manufactured by JNC Corporation),6 g of lauryl acrylate (“FA-112A”, manufactured by Hitachi Chemical Co.,Ltd.), 0.15 g of n-octyl mercaptan (manufactured by Wako Pure ChemicalIndustries, Ltd.), and 0.05 g of PERBUTYL 0 (manufactured by NOFCorporation) were charged in a screw tube, and after stirring, the screwtube was put in a water bath at 80° C. and heated for 4 hours.Subsequently, the resulting screw tube was heated in an oven at 100° C.for one hour, thereby obtaining a compound (D) which is liquid at 25° C.(number average molecular weight: 2,000).

Manufacturing Example 10

In a reactor equipped with a condenser, a thermometer, a stirrer, adropping funnel, and an air injection pipe, 978.2 parts by mass ofα,ω-polybutadiene glycol [a trade name: POLYBUTADIENE GLYCOL G-3000,manufacture by Nippon Soda Co., Ltd., content proportion of{(1,2-structural unit)/(1,4-structural unit)}=90/10, hydroxyl value=27mg-KOH/g], 0.5 parts by mass of p-methoxyphenol as a polymerizationinhibitor, and 0.05 parts by mass of dibutyltin dilaurate (a trade name:“L101”, manufactured by Tokyo Fine Chemical Co., Ltd.) as a catalystwere added. Then, the temperature was increased to 70° C. while allowingair to flow into the inside of the reactor, and thereafter, 20.3 partsby mass of 2-isocyanatoethyl methacrylate (a trade name: “KARENZ MOI”,manufactured by Showa Denko K.K.) was uniformly dropped over one hourwhile stirring at from 70 to 75° C., thereby undergoing reaction.

After completion of dropping, the reaction was carried out for 5 hours.As a result of IR measurement (infrared absorption analysis), whenvanishing of the isocyanate was confirmed, the reaction was finished toobtain polybutadiene methacrylate having a methacryloyl group in an endthereof (weight average molecular weight: 7,700). An average value ofmethacryloyl groups of this polybutadiene methacrylate per molecule(average functional group number) was 0.5 (calculated value from thecharged amount).

Incidentally, the weight average molecular weight and the number averagemolecular weight are each a value determined by undergoing gelpermeation chromatography with tetrahydrofuran (THF) as a solvent andconducting conversion using a calibration curve of standard polystyreneusing the following apparatus and measurement conditions. In fabricatingthe calibration curve, a five-sample set (a trade name, “PStQuick MP-H,PStQuick B”, manufactured by Tosoh Corporation) was used as the standardpolystyrene.

Apparatus: High-performance GPC apparatus, HCL-8320GPC (detector:differential refractometer or UV) (a trade name, manufactured by TosohCorporation)

Solvent used: Tetrahydrofuran (THF)

Column: Column TSKGEL SuperMultipore HZ-H (a trade name. manufactured byTosoh Corporation)

Column size: Column length=15 cm, column inner diameter=4.6 mm

Measurement temperature: 40° C.

Flow rate: 0.35 mL/min

Sample concentration: 10 mg/5 mL-THF

Injection amount: 20 μL

[Raw Materials]

In addition, the following raw materials were used in the Examples andComparative Examples described below.

FA-129AS: Compound of the general formula (13), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-112M: Compound of the general formula (14), a trade name,manufactured by Hitachi Chemical Co., Ltd.

EHA: Compound of the general formula (15), 2-ethylhexyl acrylate,manufactured by Wako Pure Chemical Industries, Ltd.

IM-A: Compound of the general formula (16), a trade name: “LIGHTACRYLATE IM-A” (isomer mixture of C14), manufactured by KyoeishaChemical Co., Ltd.

FA-121M: Compound of the general formula (17), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-112A: Compound of the general formula (18), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-126AS: Compound of the general formula (19), a trade name,manufactured by Hitachi Chemical Co., Ltd.

VBMA: Compound of the general formula (20), a name of an article made onan experimental basis, manufactured by Hitachi Chemical Co., Ltd.

TMP-A: Compound of the general formula (21), a trade name: “LIGHTACRYLATE TMP-A”, manufactured by Kyoeisha Chemical Co., Ltd.

FA-125M: Compound of the general formula (22), a trade name,manufactured by Hitachi Chemical Co., Ltd.

GMAG: Compound of the general formula (23), a trade name: “GMA LIGHTESTER G”, manufactured by Kyoeisha Chemical Co., Ltd.

FA-314A: Compound of the general formula (24), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-318A: Compound of the general formula (25), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-BZM: Compound of the general formula (26), a trade name, manufacturedby Hitachi Chemical Co., Ltd.

FA-BZA: Compound of the general formula (27), a trade name, manufacturedby Hitachi Chemical Co., Ltd.

FA-321A: Compound of the general formula (28), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-3218M: Compound of the general formula (29), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-321M: Compound of the general formula (30), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-323M: Compound of the general formula (31), a trade name,manufactured by Hitachi Chemical Co., Ltd.

PO-A: Compound of the general formula (32), a trade name: “LIGHTACRYLATE PO-A”, manufactured by Kyoeisha Chemical Co., Ltd.

FA-324M: Compound of the general formula (33), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-324A: Compound of the general formula (34), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-302A: Compound of the general formula (35), a trade name,manufactured by Hitachi Chemical Co., Ltd.

A-BPFE: Compound of the general formula (36), a trade name, manufacturedby Shin-Nakamura Chemical Co., Ltd.

DCP-A: Compound of the general formula (37), a trade name: “LIGHTACRYLATE DCP-A”, manufactured by Kyoeisha Chemical Co., Ltd.

FA-512M: Compound of the general formula (38), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-512AS: Compound of the general formula (39), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-513M: Compound of the general formula (40), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-513AS: Compound of the general formula (41), a trade name,manufactured by Hitachi Chemical Co., Ltd.

IB-XA: Compound of the general formula (42), a trade name: “LIGHTACRYLATE IB-XA”, manufactured by Kyoeisha Chemical Co., Ltd.

FA-511AS: Compound of the general formula (43), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-731A: Compound of the general formula (44), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-P240A: Compound of the general formula (45), a trade name,manufactured by Hitachi Chemical Co., Ltd.

FA-731AT: Compound of the general formula (46), a trade name,manufactured by Hitachi Chemical Co., Ltd.

LIGHT ACRYLATE 130A: Compound of the general formula (47), a trade name,manufactured by Kyoeisha Chemical Co., Ltd.

X-22-164AS: Compound of the general formula (48), a trade name,manufactured by Shin-Etsu Chemical Co., Ltd.

SILAPLANE TM-0701(TRIS): Compound of the general formula (49), a tradename, manufactured by JNC Corporation

PB-MOI: Compound of the general formula (50), which is obtained byallowing G-3000 (a trade name for α,ω-polybutadiene glycol, manufacturedby Nippon Soda Co., Ltd.) to react with KARENZ MOI (a trade name for2-isocyanatoethyl methacrylate, manufactured by Showa Denko K.K.)

TEAI-1000: Compound of the general formula (51), a trade name of NipponSoda Co., Ltd.

UC-102: Compound of the general formula (52), a trade name, manufacturedby Kuraray Co., Ltd., n=2, number average molecular weight: 17,000

UC-203: Compound of the general formula (52), a trade name, manufacturedby Kuraray Co., Ltd., n=3, number average molecular weight: 35,000

STC: Compound (styrene) of the general formula (53), manufactured byWako Pure Chemical Industries, Ltd.

RICON-130: Compound of the general formula (54), a trade name,manufactured by Cray Valley

RICON-131: Compound of the general formula (54), a trade name,manufactured by Cray Valley

TRIC: Compound of the general formula (55), a trade name manufactured byNippon Kasei Chemical Co., Ltd.

GBA: Glycidyl methacrylate manufactured by Kyoeisha Chemical Co., Ltd.

GEL ALL D: 1,3:2,4-Bis-O-benzylidene-D-glucitol manufactured by NewJapan Chemical Co., Ltd.

HSA: 12-Hydroxystearic acid

I-184: IRGACURE 184, 1-hydroxycyclohexyl phenyl ketone

I-189: IRGACURE 189, bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide

HPMA: 2-Hydroxypropyl methacrylate manufactured by Nippon Shokubai Co.,Ltd.

HOB: 2-Hydroxybutyl methacrylate manufactured by Kyoeisha Chemical Co.,Ltd.

POLYOIL: Liquid 1,4-polybutadiene manufactured by Zeon Corporation

PARLEAM 6: Hydrogenated polyisobutene manufactured by NOF Corporation

FA-711MM: Pentamethylpiperidyl methacrylate manufactured by HitachiChemical Co., Ltd.

TMBP (ESACURE TZT): 2,4,6-Trimethylbenzophenone manufactured by DKSHJapan K.K.

TPO: 2,4,6-Trimethylbenzoyl diphenyl phosphine oxide manufactured byBASF SE

LIQUID P: Liquid paraffin manufactured by Wako Pure Chemical Industries,Ltd.

P85 (CLEARON P-85): Terpene-based hydrogenated resin manufactured byYasuhara Chemical Co., Ltd.

PE-1 (KARENZ MT PE1): Compound of the general formula (57),pentaerythritol tetrakis(3-mercaptobutyrate) manufactured by Showa DenkoK.K.

DUP: Compound of the general formula (56), diundecyl phthalatemanufactured by J-PLUS Co., Ltd.

HBA: 4-Hydroxybutyl acrylate manufactured by Nippon Kasei Chemical Co.,Ltd.

Examples 1 to 60 Example 1

98% by mass of o-phenylphenoxyethyl acrylate (“FA-302A”, manufactured byHitachi Chemical Co., Ltd.) as the compound (A) having aphotopolymerizable functional group, 1% by mass of n-lauroyl-L-glutamicacid-α,β-dibutylamide (hereinafter referred to as “GBA”) as the oilgelling agent (B), and 1% by mass of 1-hydroxycyclohexyl phenyl ketone(manufactured by BASF SE, hereinafter referred to as “I-184”) as thephotopolymerization initiator (C) were charged in a screw tube, and thecrew tube was heated in a water bath at 90° C. to dissolve the oilgelling agent (B), thereby obtaining a photocurable resin composition(1). The obtained photocurable resin composition (1) was subjected tothe above-described evaluations. Evaluation results are shown in Table1.

Examples 2 to 60

Photocurable resin compositions were prepared in the same manner as thatin Example 1, except for changing the composition and % by mass as shownin Tables 1 to 6, and then subjected to the above-described evaluations.Evaluation results are shown in Tables 1 to 6.

Incidentally, with respect to the Examples in which the evaluationresult of the self-organization properties was “2”, the portion in aliquid state was removed, and the step height covering properties wereevaluated.

TABLE 1 Example 1 2 3 4 5 6 7 8 9 10 11 Raw material Component (A) TypeFA-302A HBA BZA BZA FA-512M DCP-A FA-314A FA-321A FA-112A TRIS 130A % bymass 98 98 98 98 98 98 98 98 98 98 98 Component (B) Type GBA GBA GEL ALLD HSA HSA HSA HSA HSA HSA HSA HSA % by mass 1 1 1 1 1 1 1 1 1 1 1Component (C) Type I-184 I-184 I-184 I-184 I-184 I-184 I-184 I-184 I-184I-184 I-184 % by mass 1 1 1 1 1 1 1 1 1 1 1 Component (D) Type — — — — —— — — — — — % by mass — — — — — — — — — — — Component (E) Type — — — — —— — — — — — % by mass — — — — — — — — — — — Evaluation Step height — A AA A A A A A A A A covering properties Self-organization — 4 4 4 2 2 4 44 3 4 4 properties Transparency — 4 4 4 4 4 4 4 3 2 1 1 Curing % 10 1415 15 5 6 5 8 6 12 6 shrinkage ratio Dielectric — 3.5 7 3.7 3.7 2.4 2.33.6 4.2 2.3 3.4 5.4 constant

TABLE 2 Example 12 13 14 15 16 17 18 19 Raw material Component (A) TypeFA-121M FA-126AS FA-129AS FA-731A FA-P240A TMP-A 164AS TAIC % by mass 9898 98 98 98 98 98 98 Component (B) Type HSA HSA HSA HSA HSA HSA HSA HSA% by mass 1 1 1 1 1 1 1 1 Component (C) Type I-184 I-184 I-184 I-184I-184 I-184 I-184 I-184 % by mass 1 1 1 1 1 1 1 1 Component (D) Type — —— — — — — — % by mass — — — — — — — — Component (E) Type — — — — — — — —% by mass — — — — — — — — Evaluation Step height covering — A A A A A AA A properties Self-organization — 3 2 4 3 2 3 4 4 propertiesTransparency — 2 2 2 2 2 1 1 4 Curing shrinkage ratio % 16 15 14 16 1318 6 13 Dielectric constant — 4.8 4.3 4 4.4 5.6 4.8 3.3 4.5

TABLE 3 Example 20 21 22 23 24 25 Raw material Component Type FA- FA-FA- FA- FA- FA- (A) 129AS 129AS 129AS 129AS 129AS 129AS % by mass 5 1010 5 2 2 Component Type HSA HSA HSA HSA HSA HSA (B) % by mass 1 1 1 1 10.5 Component Type I-184 I-184 I-184 I-184 I-184 I-184 (C) % by mass 1 11 1 1 1 Component Type Manufac- Manufac- Manufac- Manufac- Manufac-Manufac- (D) turing turing turing turing turing turing Example ExampleExample Example Example Example 3 4 4 4 4 4 % by mass 93 88 78 93 9696.5 Type — — Toluene — — — % by mass — — 10 — — — Component Type — — —— — — (E) % by mass — — — — — — Evaluation Step height — A A A A A Acovering properties Self- — 4 4 4 4 4 4 organization propertiesTransparency — 3 4 4 4 4 4 Curing % 0.7 1 1 0.7 0.3 0.3 shrinkage ratioDielectric — 4 4.1 3.8 4 3.8 3.8 constant Example 26 27 28 29 30 31 Rawmaterial Component Type FA- FA- FA- DCP-A TAIC FA- (A) 129AS 129AS 129AS129AS % by mass 2 2 2 2 5 2 Component Type HSA HSA HSA HSA HSA HSA (B) %by mass 5 1 1 1 1 1 Component Type I-184 I-184 I-184 I-184 I-184 I-184(C) % by mass 1 1 1 1 1 1 Component Type Manufac- Manufac- Manufac-Manufac- Manufac- Manufac- (D) turing turing turing turing turing turingExample Example Example Example Example Example 4 5 6 7 8 9 % by mass 9296 96 96 93 96 Type — — — — — — % by mass — — — — — — Component Type — —— — — — (E) % by mass — — — — — — Evaluation Step height — A A A A A Acovering properties Self- — 4 4 4 4 4 4 organization propertiesTransparency — 4 4 4 3 3 2 Curing % 0.3 0.3 0.3 0.3 0.5 0.3 shrinkageratio Dielectric — 3.8 3.9 3.9 3.6 3.9 4.1 constant

TABLE 4 Example 32 33 34 35 Raw material Component (A) TypeManufacturing Manufacturing Manufacturing Manufacturing Example 1Example 1 Example 2 Example 2 % by mass 98  93  98  93  Type — FA-129AS— FA-129AS % by mass — 5 — 5 Component (B) Type HSA HSA HSA HSA % bymass 1 1 1 1 Component (C) Type I-184 I-184 I-184 I-184 % by mass 1 1 11 Component (D) Type — — — — % by mass — — — — Component (E) Type — — —— % by mass — — — — Evaluation Step height covering — A A A A propertiesSelf-organization — 4 4 4 4 properties Transparency — 3 3 3 3 Curingshrinkage ratio %   0.6   1.2   0.7   1.3 Dielectric constant — 4 4  3.9   4.1

TABLE 5 Example 36 37 38 39 40 41 42 43 Raw material Component (A) TypeUC-102 UC-102 UC-102 UC-102 UC-102 UC-102 UC-102 UC-102 % by mass 98 7849 49 40 39 30 30 Type — — FA-512A FA-129AS RICON 130 RICON 130 RICON130 RICON 130 % by mass — — 49 49 58 49 58 58 Type — — — — — — FA-513MFA-512AS % by mass — — — — — — 10 10 Type — — — — — — — — % by mass — —— — — — — — Component (B) Type HSA HSA HSA HSA HSA HSA HSA HSA % by mass1 1 1 1 1 1 1 1 Component (C) Type I-184 I-184 I-184 I-184 I-184 I-184I-184 I-184 % by mass 1 1 1 1 1 1 1 1 Type — — — — — — — — % by mass — —— — — — — — Type — — — — — — — — % by mass — — — — — — — — Component (D)Type — PARLEAM 6 — — — LIQUID P — — % by mass — 20 — — — 10 — —Component (E) Type — — — — — — — — % by mass — — — — — — — — EvaluationStep height covering — A A A A A A A A properties Self-organization — 44 4 4 4 4 4 4 properties Transparency — 4 4 4 4 4 4 4 4 Curing shrinkageratio % 0.6 0.5 1 1 0.4 0.4 0.4 0.4 Dielectric constant — 2.9 2.3 3.33.5 3.3 2.8 2.7 2.7 Example 44 45 46 47 48 49 50 51 Raw materialComponent (A) Type UC-102 UC-102 UC-102 UC-203 UC-203 UC-203 UC-203UC-203 % by mass 30 30 56.4 49 49 38 56.4 63 Type RICON 130 FA-512MFA-512M FA-512M FA-129AS HOB FA-512M FA-711MM % by mass 58 10 12 49 49 512 12 Type FA-BZA — HPMA — — FA-512M HPMA HPMA % by mass 10 — 2 — — 16 22 Type — — FA-BZA — — — FA-BZA — % by mass — — 4 — — — 4 — Component (B)Type HSA HSA HSA HSA HSA HSA HSA HSA % by mass 1 1 1 1 1 1 1 1 Component(C) Type I-184 I-184 I-184 I-184 I-184 I-184 I-184 I-184 % by mass 1 10.2 1 1 3 0.2 0.5 Type — — TPO — — TPO TPO TPO % by mass — — 1.4 — — 11.4 1 Type — — — — — — — TMBP % by mass — — — — — — — 0.5 Component (D)Type — POLYOIL POLYOIL — — POLYOIL POLYOIL POLYOIL % by mass — 58 20 — —20 20 20 Component (E) Type — — P85 — — P85 P85 — % by mass — — 3 — — 163 — Evaluation Step height covering — A A A A A A A A propertiesSelf-organization — 4 4 4 4 4 4 4 4 properties Transparency — 4 4 4 4 44 4 4 Curing shrinkage ratio % 0.4 0.4 0.8 1.2 1.4 1.5 1.8 1.4Dielectric constant — 2.7 2.9 2.7 3.1 3.2 2.9 3.1 3

TABLE 6 Example 52 53 54 55 56 Raw material Component (A) Type EHAManufacturing Manufacturing Manufacturing Manufacturing Example 10Example 10 Example 10 Example 10 % by mass 49 48 48.65 45 45 TypeTEAI-1000 RICON 130 RICON 130 RICON 130 RICON 130 % by mass 49 30 30 3027 Type — — — — — % by mass — — — — — Type — — — — — % by mass — — — — —Type — — — — — % by mass — — — — — Component (B) Type HSA HSA HSA HSAHSA % by mass 1 1 0.35 4 9 Component (C) Type I-184 I-184 I-184 I-184I-184 % by mass 1 1 1 1 1 Component (D) Type — ManufacturingManufacturing Manufacturing Manufacturing Example 4 Example 4 Example 4Example 4 % by mass — 20 20 20 18 Type — — — — — % by mass — — — — —Component (E) Type — — — — % by mass — — — — — Evaluation Step heightcovering — A A A A A properties Self-organization — 4 4 4 4 4 propertiesTransparency — 4 4 4 4 3 Curing shrinkage ratio % 1 0.5 0.5 0.5 0.5Dielectric constant — 2.4 2.8 2.8 2.8 2.8 Example 57 58 59 60 Rawmaterial Component (A) Type Manufacturing Manufacturing ManufacturingManufacturing Example 10 Example 10 Example 10 Example 10 % by mass 6844 44 34.5 Type — IBXA IBXA IBXA % by mass — 20 20 5 Type — RICON 130 —FA-314A % by mass — 30 — 10 Type — — — RICON 130 % by mass — — — 10 Type— — — RICON 131 % by mass — — — 35 Component (B) Type HSA HSA HSA HSA %by mass 1 1 1 1 Component (C) Type I-184 I-184 I-184 I-819 % by mass 1 11 0.5 Component (D) Type Manufacturing PE-1 PE-1 PE-1 Example 4 % bymass 30 4 4 4 Type — — DUP — % by mass — — 30 — Component (E) Type — — —— % by mass — — — — Evaluation Step height covering — A A A A propertiesSelf-organization — 4 4 4 4 properties Transparency — 4 4 4 4 Curingshrinkage ratio % 0.7 1 0.9 0.9 Dielectric constant — 3.2 2.8 3.2 2.8

Examples 61 to 105 and Reference Examples 1 and 2 Examples 61 to 105

99 parts by mass of each of the compounds (A) having aphotopolymerizable functional group represented by the general formulae(13) to (55) and 1 part by mass of 12-hydroxystearic acid (B) as the oilgelling agent were charged in a 2-mL screw tube, and the screw tube washeated in a water bath at 90° C. to dissolve the 12-hydroxystearic acid.Thereafter, the evaluation of self-organization properties and theevaluation of transparency were carried out. Evaluation results areshown in FIGS. 4 to 8.

However, since the compounds (A) marked with a * symbol in FIGS. 4 to 9,namely the compounds of the general formulae (31) and (36) in FIG. 5,the compounds of the general formulae (44) and (46) in FIG. 7, thecompounds of the general formulae (50) to (52) in FIG. 8 have a highviscosity, each of these compounds was diluted to 50% by mass with LIGHTACRYLATE DCP-A (a trade name for dimethylol tricyclodecane diacrylate,manufactured by Kyoeisha Chemical Co., Ltd.). That is, as for thesecompounds, each of the compounds was diluted with DCP-A such that thecontent thereof was 50% by mass in the total amount of the compound andDCP-A, and then subjected to the same evaluations.

In addition, after carrying out the evaluation of self-organizationproperties and the evaluation of transparency, the evaluation of stepheight covering properties was also carried out. As a result, in all ofExamples 61 to 105, it was confirmed that filling was achieved leavingno air gap in the level difference part without causing leakage.Incidentally, with respect to the Examples in which the evaluationresult of the self-organization properties was “2”, the portion in aliquid state was removed, and the step height covering properties wereevaluated.

Reference Examples 1 and 2

With respect to the compounds (D) of the general formulae (56) and (57),the same operations as those in Example 61 were carried out. Theevaluation results are shown in FIG. 9. Incidentally, these compounds(D) of the general formulae (56) and (57) were not diluted with DCP-A.

INDUSTRIAL APPLICABILITY

Since the photocurable resin composition according to the presentinvention hardly causes leakage and is easily formed into a desiredshape, it is widely used as an adhesive; a pressure-sensitive adhesive;a filler; an optical member such as an optical wave guide, a member forsolar batteries; a light emitting diode (LED), a phototransistor, aphotodiode, an optical semiconductor element, an image display device,an illumination device, etc.; a dental material; and the like.

In particular, the photocurable resin composition according to thepresent invention makes it possible to manufacture a resin compositionhaving excellent step height covering properties. In addition, when thephotocurable resin composition according to the present invention islaminated and then crosslinked, it is able to enhance adhesive strengthand holding power and reveal high reliability. Accordingly, thephotocurable resin composition according to the present invention issuited for an application of an image display device, and in particular,it is extremely useful as a material for filling a layer-to-layer spacebetween a panel such as a touch panel, etc. and a transparent protectiveplate such as a glass substrate, etc.

EXPLANATIONS OF LETTERS OR NUMERALS

-   -   7: Image display unit    -   10: Liquid crystal display cell    -   20: Polarizing plate    -   22: Polarizing plate    -   30: Touch panel    -   31: Transparent resin layer    -   32: Transparent resin layer    -   40: Transparent protective plate (protective panel)    -   50: Backlight system    -   60: Level difference part

What is claimed is:
 1. A method for manufacturing an image displaydevice comprising allowing a photocurable resin composition to intervenein a gap between a touch panel and a transparent protective plate andcuring the photocurable resin composition, wherein the photocurableresin composition containing a compound (A) having a photopolymerizablefunctional group and an oil gelling agent (B) is allowed to intervene inthe gap and cured upon irradiation with light at least from the side ofthe transparent protective plate.
 2. The method for manufacturing animage display device according to claim 1, wherein the transparentprotective plate has a level difference part.
 3. The method formanufacturing an image display device according to claim 1, wherein theoil gelling agent (B) is at least one member of a hydroxy fatty acid,dextrin ester of fatty acid, n-lauroyl-L-glutamic acid-α,β-dibutylamide,di-p-methylbenzylidene sorbitol glucitol,1,3:2,4-bis-O-benzylidene-D-glucitol,1,3:2,4-bis-O-(4-methylbenzylidene)-D-sorbitol,bis(2-ethylhexanoato)hydroxyaluminum, and compounds represented by thefollowing general formulae (1) to (12):

wherein in the general formula (1), m is an integer of from 3 to 10; nis an integer of from 2 to 6; R₁ is a saturated hydrocarbon group havinga carbon number of from 1 to 20; and X is sulfur or oxygen, in thegeneral formula (2), R₂ is a saturated hydrocarbon group having a carbonnumber of from 1 to 20; and Y₁ is a bond or a benzene ring, in thegeneral formula (3), R₃ is a saturated hydrocarbon group having a carbonnumber of from 1 to 20; and Y₂ is a bond or a benzene ring, in thegeneral formula (4), R₄ is a saturated hydrocarbon group having a carbonnumber of from 1 to 20, in the general formula (6), R₅ and R₆ are eachindependently a saturated hydrocarbon group having a carbon number offrom 1 to 20, in the general formula (7), R₇ is a saturated hydrocarbongroup having a carbon number of from 1 to 20, in the general formula(8), R₈ is a saturated hydrocarbon group having a carbon number of from1 to 20, and in the general formula (10), R₉ and R₁₀ are eachindependently a saturated hydrocarbon group having a carbon number offrom 1 to
 20. 4. The method for manufacturing an image display deviceaccording to claim 1, wherein the compound (A) having aphotopolymerizable functional group includes a compound having anethylenically unsaturated group.
 5. The method for manufacturing animage display device according to claim 1, wherein the photocurableresin composition further contains a photopolymerization initiator (C).6. The method for manufacturing an image display device according toclaim 1, wherein the photocurable resin composition further contains acompound (D) which is liquid at 25° C.
 7. The method for manufacturingan image display device according to claim 1, wherein the photocurableresin composition further contains a compound (E) which is solid at 25°C.
 8. The method for manufacturing an image display device according toclaim 1, wherein the touch panel is a resistive membrane system, anelectrostatic capacitance type, or an inductive coupling type.